Disulfur dichloride

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Disulfur dichloride
IUPAC name sulfur dichloride
Other names dichlorosulfane
Identifiers
InChI InChI=1/Cl2S2/c1-3-4-2
InChIKey PXJJSXABGXMUSU-UHFFFAOYAK
Standard InChI InChI=1S/Cl2S2/c1-3-4-2
Standard InChIKey PXJJSXABGXMUSU-UHFFFAOYSA-N
CAS number [10025-67-9]
EC number 233-036-2
ChemSpider 23192
Properties[1]
Chemical formula S2Cl2
Molar mass 135.04 g mol−1
Appearance yellow liquid
Density 1.677 g cm−3
Melting point

−76 °C

Boiling point

138 °C

Solubility in water reacts violently
Structure[1]
Molecular geometry bent; S–S = 195 pm, S–Cl = 206 pm, Cl–S–S = 107.7°, dihedral = 85.2°
Thermochemistry[2]
Std enthalpy of formation ΔfHo298 −58.16 kJ mol−1
Standard molar entropy So298 223.84 J K−1 mol−1
Hazards[3]
Material safety data sheet (MSDS) ICSC 0958
EU index number 016-012-00-4
GHS pictograms Skin Corr. 1AAcute Tox. 3, 4Aquatic Acute 1
GHS signal word DANGER
GHS hazard statements H301, H332, H314, H400
Related compounds
Other anions Disulfur difluoride
Disulfur dibromide
Disulfur diiodide
Other cations Diselenium dichloride
Other chlorides of sulfur Sulfur dichloride
Sulfur tetrachloride
Thionyl chloride
Sulfuryl chloride
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Disulfur dichloride, S2Cl2, is the most common chloride of sulfur.

Notes and references

Notes

References

  1. 1.0 1.1 Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 815–16, 820. ISBN 0-08-022057-6.
  2. Disulfur dichloride. In NIST Chemistry WebBook; National Institute for Standards and Technology, <http://webbook.nist.gov/cgi/inchi/InChI%3DInChI=1S/Cl2S2/c1-3-4-2>. (accessed 17 September 2010).
  3. Index no. 016-012-00-4 of Annex VI, Part 3, to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. OJEU L353, 31.12.2008, pp 1–1355 at p 399.

External links

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