| Barium bromide
|
| Identifiers
|
| InChI |
InChI=1/Ba.2BrH/h;2*1H/q+2;;/p-2
|
| InChIKey |
NKQIMNKPSDEDMO-NUQVWONBAE
|
| Standard InChI |
InChI=1S/Ba.2BrH/h;2*1H/q+2;;/p-2
|
| Standard InChIKey |
NKQIMNKPSDEDMO-UHFFFAOYSA-L
|
| CAS number |
[10553-31-8]
|
| EC number |
234-140-0
|
| ChemSpider |
59728
|
| Properties[1]
|
| Chemical formula |
BaBr2
|
| Molar mass |
297.14 g mol−1
|
| Appearance |
white crystalline solid
|
| Density |
4.781 g cm−3
|
| Melting point |
847 °C
|
| Solubility in water |
104.1 g/100 g (20 °C)
|
| Thermochemistry[2]
|
Std enthalpy of formation ΔfHo298 |
−757.72 kJ mol−1
|
Standard molar entropy So298 |
148.53 J K−1 mol−1
|
| Hazards[3][4]
|
| EU index number |
056-002-00-7
|
| GHS pictograms |
|
| GHS signal word |
WARNING
|
| GHS hazard statements |
H302, H332
|
| GHS precautionary statements |
P261, P264, P270, P271, P301+312, P304+340, P330, P501
|
| PEL (U.S.) |
0.5 mg m−3 TWA (as Ba)
|
| Related compounds
|
| Other anions |
Barium fluoride
Barium chloride
Barium iodide
|
| Other cations |
Beryllium bromide
Magnesium bromide
Calcium bromide
Strontium bromide
Radium bromide
|
| Other compounds |
Barium hypobromite
Barium bromite
Barium bromate
Barium perbromate
|
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
|
|
| Barium bromide dihydrate
|
| Identifiers
|
| InChI |
InChI=1/Ba.2BrH.2H2O/h;2*1H;2*1H2/q+2;;;;/p-2
|
| InChIKey |
HQQMRSGBIPFNSN-NUQVWONBAC
|
| Standard InChI |
InChI=1S/Ba.2BrH.2H2O/h;2*1H;2*1H2/q+2;;;;/p-2
|
| Standard InChIKey |
HQQMRSGBIPFNSN-UHFFFAOYSA-L
|
| CAS number |
[7791-28-8]
|
| EC number |
234-140-0
|
| ChemSpider |
21241341
|
| Properties[1]
|
| Chemical formula |
BaBr2·2H2O
|
| Molar mass |
333.17 g mol−1
|
| Appearance |
white crystalline solid
|
| Density |
3.58 g cm−3
|
| Melting point |
75 °C dehydr.
|
| Solubility in water |
151 g/100 g (20 °C)
|
| Hazards[3][4]
|
| EU index number |
056-002-00-7
|
| GHS pictograms |
|
| GHS signal word |
WARNING
|
| GHS hazard statements |
H302, H332
|
| GHS precautionary statements |
P261, P264, P270, P271, P301+312, P304+340, P330, P501
|
| PEL (U.S.) |
0.5 mg m−3 TWA (as Ba)
|
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
|
|
Barium bromide, BaBr2, is a binary compound of barium and bromine. It is used for producing other bromides[5] and as an X-ray storage phosphor.[6][7][8]
Notes and references
Notes
References
- ↑ 1.0 1.1 CRC Handbook of Chemistry and Physics, 62nd ed.; Weast, Robert C., Ed.; CRC Press: Boca Raton, FL, 1981; p B-80. ISBN 0-8493-0462-8.
- ↑ Barium dibromide. In NIST Chemistry WebBook; National Institute for Standards and Technology, <http://webbook.nist.gov/cgi/inchi/InChI%3D1S/Ba.2BrH/h;2*1H/q+2;;/p-2>. (accessed 8 January 2011).
- ↑ 3.0 3.1 Index no. 056-002-00-7 of Annex VI, Part 3, to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. OJEU L353, 31.12.2008, pp 1–1355 at p 438.
- ↑ 4.0 4.1 "Barium, soluble compounds (as Ba)" in 29 C.F.R. § 1910.1000 Table Z-1, 54 FR 36767, September 5, 1989, as amended.
- ↑ Ukeles, S. D.; Freiberg, M. Bromine, Inorganic Compounds. In Kirk-Othmer Encyclopedia of Chemical Technology; John Wiley: New York, 2002. DOI: 10.1002/0471238961.021815131001031.
- ↑ Nensel, B.; Thielemann, P.; Decker, G. Are storage phosphors a useful tool for soft x-ray imaging diagnostics? Spectral sensitivity and spatial resolution in the 0.07 to 14 nm range. J. Appl. Phys. 1998, 83 (4), 2276–81. DOI: 10.1063/1.366968.
- ↑ Thoms, M. An improved X-ray detector for use at synchrotrons. Nucl. Instrum. Methods Phys. Res., Sect. A 1998, 413 (1), 175–84. DOI: 10.1016/S0168-9002(98)00199-5.
- ↑ Edgar, A.; Secu; Williams, G. V. M.; Schweizer, S.; Spaeth, J.-M. Structural phase changes in barium bromide nano-crystals in a fluorobromozirconate glass-ceramic x-ray storage phosphor. J. Phys.: Condens. Matter 2001, 13 (28), 6259–70. DOI: 10.1088/0953-8984/13/28/308.
Further reading
External links
